2-Chloro-5-(chloromethyl)pyridine
نویسندگان
چکیده
The title compound, C(6)H(5)Cl(2)N, is almost planar, with an r.m.s. deviation of 0.0146 Å for all atoms except for the 5-choloromethyl Cl atom. The offset Cl atom lies above this plane with a Cl-C-C angle of 111.11 (17)°. In the crystal, mol-ecules are connected via inter-molecular C-H⋯N hydrogen bonds, forming dimers.
منابع مشابه
1,6-Bis(chloromethyl)pyridine
In the title compound, C(7)H(7)Cl(2)N, a halogenated derivative of 2,6-lutidine, the C-Cl vectors of the chloro-methyl groups point at opposite sides of the aromatic plane to each other. A weak dispersive Cl⋯Cl contact [3.4342 (3) Å] connects the mol-ecules into a chain along the [101] direction. A π-π inter-action with a centroid-centroid distance of 3.7481 (5) Å is also observed.
متن کامل2-Chloro-5-chloromethyl-1,3-thiazole
In the title compound, C(4)H(3)Cl(2)NS, the chloro-methyl C and 2-position Cl atoms lie close to the mean plane of the thia-zole ring [deviations = 0.0568 (2) and 0.0092 (1) Å, respectively]. No classical hydrogen bonds are found in the crystal structure.
متن کامل7-Chloro-5-(chloromethyl)pyrazolo[1,5-a]pyrimidine-3-carbonitrile
All non-H atoms of the title compound, C(8)H(4)Cl(2)N(4), are essentially coplanar, with an r.m.s. deviation of 0.011 Å. In the crystal, weak C-H⋯N hydrogen bonds link the mol-ecules into infinite sheets parallel to the bc plane.
متن کامل5-(Chloromethyl)quinolin-8-yl acetate
The title compound, C(12)H(10)ClNO(2), crystallizes with two independent mol-ecules in the asymmetric unit; these are approximate mirror images of each other. In each mol-ecule, the chloro-methyl and acetate groups lie on the same side of the quinoline ring system, with dihedral angles between the ring plane and the plane of the acetate group of 82.0 (1) and -79.2 (1)°. The C-C-C-Cl torsion ang...
متن کامل2-Amino-5-chloropyridine–fumaric acid (1/2)
The asymmetric unit of the title compound, C(5)H(5)ClN(2)·0.5C(4)H(4)O(4), comprises a neutral 2-amino-5-chloro-pyridine mol-ecule and one half of a fumaric acid mol-ecule which lies on an inversion center. The dihedral angle between the pyridine ring and the plane formed by the fumaric acid mol-ecule is 3.22 (8)°. The 2-amino-5-chloro-pyridine mol-ecule is planar, with a maximum deviation of 0...
متن کامل